N-Methyl-4-(4-pivalamidophenylsulfanyl)picolinamide hemihydrate
نویسندگان
چکیده
منابع مشابه
N-Methyl-4-(4-pivalamidophenylsulfanyl)picolinamide hemihydrate
In the title compound, C(18)H(21)N(3)O(2)S·0.5H(2)O, the benzene ring makes dihedral angles of 88.59 (6) and 40.74 (8)° with the pyridine ring and the amide group, respectively. The water O atom lies on a twofold axis. In the crystal, the organic mol-ecules and the water mol-ecules are linked via O-H⋯O hydrogen bonds, while the organic mol-ecules are connected to each other via N-H⋯O hydrogen b...
متن کاملN-(2,4-Difluorophenyl)-5-methyl-1,2-oxazole-4-carboxamide hemihydrate
In the title compound, C(11)H(8)F(2)N(2)O(2)·0.5H(2)O, the dihedral angle between the benzene and isoxazole rings is 8.08 (3)°. In the crystal, the components are linked by O-H⋯N and N-H⋯O hydrogen bonds, in which the water mol-ecule acts as both a donor and an acceptor, into a tape with an R(4) (4)(16) graph-set motif along the a axis. The water mol-ecule is located on a twofold rotation axis....
متن کامل(N 4-n-Butylpyridine-4-carbothioamide-κN 4)chloridobis(dimethylglyoximato-κ2 N,N′)cobalt(III) hemihydrate
The title compound, trans-[Co(C(4)H(7)N(2)O(2))(2)Cl(C(10)H(14)N(2)S)]·0.5H(2)O, contains two independent mol-ecules in the asymmetric unit in which the Co(III) ions are coordinated in slightly distorted octa-hedral coordination environments. The bis-chelating glyoximate ligands, which occupy equatorial sites, are linked by interligand O-H⋯O hydrogen bonds. The dihedral angles between the mean ...
متن کامل(E)-N′-[4-(Dimethylamino)benzylidene]-4-hydroxybenzohydrazide hemihydrate
In the title compound, C(16)H(17)N(3)O(2)·0.5H(2)O, the two hydrazide mol-ecules are approximately planar: the dihedral angles between the two substituted benzene rings are 7.7 (2) and 4.2 (2)°. Both hydrazone mol-ecules exist in a trans geometry with respect to their methyl-idene units. In the crystal, the water mol-ecule lies between the two organic mol-ecules and makes bifurcated O-H⋯(N,O) h...
متن کاملN-(4-Aminophenyl)-1,8-naphthalimide hemihydrate
The title compound, C(18)H(12)N(2)O(2)·0.5H(2)O, was prepared by the reaction of 1,4-phenyl-enediamine with 1,8-naphthalic anhydride in refluxing dimethyl-formamide. The structure is stabilized by N-H⋯O and O-H⋯O hydrogen bonds. There are π-π stacking inter-actions [centroid-centroid distances of 3.718 (2), 3.510 (2) and 3.546 (2) Å] and C-H⋯π inter-actions between the mol-ecules. The water mol...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2011
ISSN: 1600-5368
DOI: 10.1107/s1600536811012268